| 双氮-苯硫脲C_(14)H_(14)N_4S_2的合成及晶体结构、光学和电化学性质 |
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| 引用本文： | 李颖,汪庆祥.双氮-苯硫脲C_(14)H_(14)N_4S_2的合成及晶体结构、光学和电化学性质[J].青岛科技大学学报,2006,27(2):119-123. |
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| 作者姓名： | 李颖 汪庆祥 |
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| 作者单位： | 青岛科技大学配位化学所 山东青岛266042(李颖)，青岛科技大学化学与分子工程学院 山东青岛266042(汪庆祥) |
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| 摘 要： | 合成了标题化合物双氮-苯硫脲(BPTU,C14H14N4S2),并通过X射线衍射对其单晶结构进行了测定。该化合物属于单斜晶系,C2/c空间群,晶胞参数为a=2.692 4(7)nm,b=0.632 8(13)nm,c=0.944 5(19)nm,β=105.91(3)°,z=4。标题化合物具有缩氨基硫脲的顺式结构并且其分子结构略微歪斜,由于N H…S等分子间氢键作用,使得分子结构更趋稳定。通过红外光谱(IR)、紫外-可见光谱(UV-Vis)及循环伏安法(CV)等方法对化合物的光学性质和电化学性质进行了表征。
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| 关 键 词： | 双氮-苯硫脲 晶体结构 红外光谱 紫外-可见光谱 电化学性质 |
| 文章编号： | 1672-6987(2006)02-0119-04 |
| 修稿时间： | 2005年9月2日 |
Synthesis,Crystal Structure, Spectroscopic and Electrochemical Properties of Bis(N-phenylthiourea) |
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| LI Ying,WANG Qing-xiang.Synthesis,Crystal Structure, Spectroscopic and Electrochemical Properties of Bis(N-phenylthiourea)[J].Journal of Qingdao University of Science and Technology:Natutral Science Edition,2006,27(2):119-123. |
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| Authors: | LI Ying WANG Qing-xiang |
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| Abstract: | The title compound of bis(N-phenylthiourea)(BPTU) was synthesized and its crystal structure was characterized by X-ray diffraction.The compound crystallizes in monoclinic crystal system,space group C2/c with a= 2.692 4(7) nm,b=0.632 8(13) nm,c=0.944 5(19) nm,β=105.91(3)°,z=4.The title compound has cis-configuration of the thiosemicarbazone moiety and skew conformation of the molecule.The molecular structure and packing are stabilized by N-H…S intermolecular hydrogen-bond interaction.The spectroscopic and electrochemical properties of the compound were measured by IR,UV-Vis and Cyclic Voltammetry methods. |
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| Keywords: | bis(N-phenylthiourea) crystal structure IR UV-Vis electrochemical properties |
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