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n型(AgSbTe2)x(PbTe)1-x热电材料的制备和性能
引用本文:鄢永高,唐新峰,刘海君,尹玲玲,张清杰. n型(AgSbTe2)x(PbTe)1-x热电材料的制备和性能[J]. 武汉理工大学学报, 2007, 29(11): 1-3
作者姓名:鄢永高  唐新峰  刘海君  尹玲玲  张清杰
作者单位:武汉理工大学材料复合新技术国家重点实验室,武汉,430070
基金项目:国家自然科学基金;高校科技创新工程项目
摘    要:采用熔融缓冷法制备了组成为(AgSbTe2)x(PbTe)1-x(x=0.04—0.20)的热电材料,研究了AgSbTe2固溶量对材料微观结构和热电传输性能的影响。结果表明,当AgSbTe2固溶量增大时,样品易发生相结构偏析,样品由富Pb和富AgSb的两相组成。样品热导率随AgSbTe2固溶量增加而降低,电性能也有一定程度的降低。样品的无量纲热电优值(ZT)随AgSbTe2固溶量的减小而增加。

关 键 词:热电  熔融缓冷法  偏析
文章编号:1671-4431(2007)11-0001-03
修稿时间:2007-06-12

Preparation and Properties of n-type (AgSbTe2)x( PbTe)1-x Thermoelectric Material
YAN Yong-gao,TANG Xin-feng,LIU Hai-jun,YIN Ling-ling,ZHANG Qing-jie. Preparation and Properties of n-type (AgSbTe2)x( PbTe)1-x Thermoelectric Material[J]. Journal of Wuhan University of Technology, 2007, 29(11): 1-3
Authors:YAN Yong-gao  TANG Xin-feng  LIU Hai-jun  YIN Ling-ling  ZHANG Qing-jie
Affiliation:State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China
Abstract:(AgSbTe2)x(PbTe)1-x(x=0.04-0.20) samples were prepared by slow-cool-from-melts and the influences of AgSbTe2 content on the microstructure and thermoelectric properties were investigated.Results indicated that phase segregation occurs as x increases and the samples are characterized by a bi-phased material containing one main Pb-rich phase and another Ag-Sb-rich phase.As AgSbTe2 content increases,the thermal conductivity is depressed and the electrical properties decrease to some extent.The dimensionless of figure of merits(ZT) is greater for sample with a lower AgSbTe2 content.
Keywords:(AgSbTe2)x(PbTe)1-x
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