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Removal of Organophosphorus Pesticides from Aqueous Solution by Using Adsorptive Bubble Separation Techniques
Abstract:Abstract

Two organophosphorus pesticides, ddvp (phosphoric acid 2,2-dichlorovinyl dimethyl ester) and phorate (phosphorodithioic acid o,o-diethyl s-[(ethylthio)methyl] ester) were removed from aqueous solution by three adsorptive bubble separation techniques: air stripping, solvent sublation, and adsorbing colloid flotation. The effects of pH, flow rate, surfactant, ethanol, ionic strength, and coprecipitant concentration on the efficiency of pesticide removal were studied. Over 97% of phorate was removed in 30 min by solvent sublation, and 90% of phorate was removed in 10 min by adsorbing colloid flotation with Fe(OH)3, floc. The separations of ddvp by these techniques were not effective.
Keywords:2,3-Butanediol  Vacuum membrane distillation  Fermentation  Recovery
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