| [Ag(PPh_3)_2(CH_3COO)]_2·3H_2O的合成和晶体结构 |
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| 引用本文： | 农平声,黄丽红,周益峰,陈晓红,楼纪东,卢秀莲.[Ag(PPh_3)_2(CH_3COO)]_2·3H_2O的合成和晶体结构[J].中国计量学院学报,2011,22(2):185-188. |
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| 作者姓名： | 农平声 黄丽红 周益峰 陈晓红 楼纪东 卢秀莲 |
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| 作者单位： | 1. 中国计量学院生命科学学院,浙江杭州,3100018
2. 北京化工大学化工资源有效利用国家重点实验室,北京,100029 |
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| 基金项目： | 国家教育部留学回国人员资助项目，人事部留学回国人员择优资助项目，浙江省教育厅资助项目 |
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| 摘 要： | 将醋酸银和三苯基磷按1∶2摩尔比例进行反应得到化合物Ag(PPh3)2(CH3COO)]2,采用红外光谱、核磁共振、元素分析和单晶X射线衍射的方法,对其结构进行了表征.晶体结构解析结果显示,配合物属单斜晶系,空间群C2/c,a=44.286 8',b=13.269 6',c=24.997 0',α=90.000°,β=105.573°,γ=90.000°,Z=8,R=0.052 0,wR2=0.132 4.
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| 关 键 词： | 银配合物 核磁共振 晶体结构 |
Synthesis and crystal structure of [Ag ( PPh3 ) 2 (CH3 COO) ] 23H2O |
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| NONG Ping-sheng,HUANG Li-hong,ZHOU Yi-feng,CHEN Xiao-hong,LOU Ji-dong,LU Xiu-lian.Synthesis and crystal structure of [Ag ( PPh3 ) 2 (CH3 COO) ] 23H2O[J].Journal of China Jiliang University,2011,22(2):185-188. |
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| Authors: | NONG Ping-sheng HUANG Li-hong ZHOU Yi-feng CHEN Xiao-hong LOU Ji-dong LU Xiu-lian |
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| Affiliation: | NONG Ping-sheng1,HUANG Li-hong1,ZHOU Yi-feng1,CHEN Xiao-hong2,LOU Ji-dong1,LU Xiu-lian1(1.College of Life Sciences,China Jiliang University,Hangzhou 310018,China,2.State Key Laboratory of Chemical Engineering,Beijing University of Chemical Technology,Beijing 100029,China) |
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| Abstract: | The complex Ag(PPh3)2(CH3COO)]2·3H2O was obtained by the reaction of silver acetate and triphenylphosphine,its structure was characterized by IR,NMR,elemental analysis and single crystal X-ray diffraction.The results of the crystallographic analysis showed that the complex is triclinic,with space group C2/c,a=44.286 8',b=13.269 6',c=24.997 0',α=90.000°,β=105.573°,γ=90.000°,Z=8,R=0.052 0,wR2=0.132 4. |
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| Keywords: | silver complex synthesis NMR single crystal X-ray diffraction |
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