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Induced NH2 bonding of carbon nanotubes using NH3 plasma-enhanced chemical vapor deposition
Authors:Ai-Huei Chiou  Yu-Ming Chang  Wen-Fa Wu  Chang-Ping Chou  Chun-Yao Hsu
Affiliation:(1) Department of Mechanical Engineering, National Chiao Tung University, Hsinchu, Taiwan, ROC;(2) Institute of Nuclear Energy Research, Atomic Energy Council, Executive Yuan, Taoyuan, Taiwan, ROC;(3) National Nano Device Laboratories, Hsinchu, Taiwan, ROC;(4) Department of Mechanical Engineering, Lunghwa University of Science and Technology, Kueishan, Taiwan, ROC;
Abstract:Plasma-enhanced chemical vapor deposition was used to modify the multiwall carbon nanotubes (MWCNTs) using ammonia (NH3) plasma. For various durations of NH3 plasma treatment, a scanning electron microscope, X-ray, Raman spectroscopy and contact angle measurement were used to ascertain several characteristics of the MWCNTs. The experimental results show that: (1) the length of the MWCNTs is reduced, if the duration of the plasma treatment is increased; (2) the NH3 plasma treatment can incorporate amine (NH2 ) or amino (NH) functional groups onto the MWCNT surface; (3) the plasma treated carbon nanotubes become more hydrophilic.
Keywords:
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