过氧化氢选择氧化合成精细化学品研究进展

综述了国内外近几年来过氧化氢选择氧化合成精细化学品方面的最新研究进展,分别从烯烃的环氧化、醛酮的氧化、烃类的选择氧化、烯烃的氧化裂解等方面评述了过氧化氢在催化氧化反应中应用的研究概况,并对过氧化氢在不同氰化过程中的氧化机理以及在催化氧化反应应用中存在的问题进行了探讨,提出了进一步提高过氧化氢的利用率以及在反应体系中原位生成过氧化氢是今后的主要发展方向。

Progress in Synthesis of Fine Chemicals with Hydrogen Peroxide as Selective Oxidant

The recent development in synthesis of fine chemicals by using aqueous hydrogen peroxide as oxidant was reviewed. The applications of hydrogen peroxide in the epoxidation of olefin, selective oxidation of olefin,aldehyde,ketone and alkane,and the oxidation mechanism were summarized. Attention was also paid to relevant existing problems in use of hydrogen peroxide. Efficiency in usage of hydrogen peroxide and in-situ formation of hydrogen peroxide in the reaction system are two potential orientations in this field.