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Properties of GaN epitaxial layers grown on 6H-SiC(0001) by plasma-assisted molecular beam epitaxy
Authors:C D Lee  V Ramachandran  A Sagar  R M Feenstra  D W Greve  W L Sarney  L Salamanca-Riba  D C Look  Song Bai  W J Choyke  R P Devaty
Affiliation:(1) Department of Physics, Carnegie Mellon University, 15213 Pittsburgh, Pennsylvania;(2) Department of Electrical and Computer Engineering, Carnegie Mellon University, 15213 Pittsburgh, PA;(3) Materials and Nuclear Engineering Department, University of Maryland, 20742-2115 College Park, MD;(4) Wright State University of Air Force Research Laboratory, 45435 Dayton, Ohio;(5) Department of Physics and Astronomy, University of Pittsburgh, 15260 Pittsburgh, Pennsylvania;(6) Present address: IBM Microelectronics, 05452 Essex Junction, Vermont
Abstract:The structural, electrical, and optical properties of GaN grown on 6H-SiC(0001) substrates by molecular beam epitaxy are studied. Suitable substrate preparation and growth conditions are found to greatly improve the structural quality of the films. Threading dislocation densities of about 3×109 cm−2 for edge dislocations and <1×106 cm−2 for screw dislocations are achieved in GaN films of 0.8 μm thickness. Mechanisms of dislocation generation and annihilation are discussed. Increasing the Ga to N flux ratio used during growth is found to improve the surface morphology. An unintentional electron concentration in the films of about 5×1017 cm−3 is observed, and is attributed to excess Si in the films due to a Si-cleaning step used in the substrate preparation. Results from optical characterization are correlated with the structural and electronic studies.
Keywords:GaN  SiC  molecular beam epitaxy  dislocation density  scanning tunneling microscopy
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