氨基磺酸盐系高效减水剂的改性研究

氨基磺酸盐系减水剂具有高减水率、抑制混凝土塌落度经时损失等优点,但泌水严重,限制了其在混凝土中的应用。本文根据“分子设计”原则,通过单体A和单体U引入适当的官能团,对传统氨基磺酸盐系高效减水剂进行改性,测试了产品对水泥净浆流动度、流动度经时损失和泌水率的影响。试验表明,单体A的改性效果优于单体U,以9%的单体A改性后,减水剂的分散性和分散保持性能好,泌水率显著降低。

Study on Modification of Amino-sulfonic Acid-based Water-reducer

Amino-sulfonic acid-based water-reducer is characterized by high water-reducing rate and restraining the concrete mixture from slump loss with time. The application of amino-sulfonic acid-based waterreducer in concrete mixture was restricted due to its high bleeding. Based on principles of molecular design, the traditional superplasticizer of aminosulfonic acid series was modified by the suitable functional group introduced by monomer A and monomer U. The effects of such product on the fluidity, fluidity loss with time and bleeding rate of cement paste were tested. It was found that the modifying effect of monomer A for the superplasticizer was better than that of monomer U. The dispensability and flow retainability of superplasticizer were strong and the bleeding rate of cement paste added with superplasticizer modified by 9% monomer A was reduced obviously.