Affiliation: | a Department of Chemistry, Odense University, DK-5230, Odense M, Denmark b Quantum Theory Project, University of Florida, Gainesville, FL 32611, USA |
Abstract: | Using the random phase approximation, we have calculated the total and directional components of the mean excitation energy for stopping (I0) and the stopping anisotropy (
) as well as the first moment (I1) of the dipole oscillator strength distribution for 20 small molecules and molecular ions containing 6 to 30 electrons. We find that for excitations polarized orthogonal (perpendicular) and parallel to the molecular high symmetry axis I0O > I0P for all linear molecules, while I1O < I1P for all molecules other than HF. We note that the Bloch rule holds only for small, compact molecules, and that the Bragg rule should not be used to determine the mean excitation energies of the molecules that we consider here. The stopping anisotropy is positive for all but the C3v molecules, and is largest for the linear, rod-shaped molecules. |