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Synthesis of Pb(Ni1/3Nb2/3)0.72Ti0.28O3 perovskite ceramics by a reaction-sintering process
Authors:Yi-Cheng Liou  Jen-Hsien Chen  Yi-Chen Huang  Chi-Ting Wu  Yow-Renn Chen
Affiliation:(1) Department of Electronic Engineering, Kun-Shan University, Tainan Hsien, Taiwan, R.O.C.
Abstract:Pb(Ni1/3Nb2/3)0.72Ti0.28O3 (PNNT) perovskite ceramics produced by a reaction-sintering process were investigated. Without any calcination, the mixture of PbO, Ni(NO3)2, Nb2O5 and TiO2 was pressed and sintered directly into PNNT ceramics. PNNT ceramics of 100% perovskite phase were obtained. For PNNT sintered for 2 h in PbO compensated atmosphere, maximum density reaches a value 8.49 g/cm3 (99.8% of the theoretical value) at 1250C. A maximum dielectric constant 20600 occurred around 37C at 1 kHz in PNNT sintered at 1250C for 2 h.
Keywords:PNN-PT  Dielectric  Reaction-sintering process
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