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哌嗪改性聚醚基聚二甲基硅氧烷的合成与应用性能研究
引用本文:安秋凤 黄良仙 李临生 杜经武. 哌嗪改性聚醚基聚二甲基硅氧烷的合成与应用性能研究[J]. 陕西科技大学学报, 2004, 22(4): 13-16
作者姓名:安秋凤 黄良仙 李临生 杜经武
作者单位:陕西科技大学化学与化工学院,陕西科技大学化学与化工学院,陕西科技大学化学与化工学院,陕西科技大学化学与化工学院 陕西咸阳 712081,陕西咸阳 712081,陕西咸阳 712081,陕西咸阳 712081
基金项目:陕西省自然科学计划发展重点项目,项目编号:2002K08-G10
摘    要:利用哌嗪与自制的聚醚/环氧硅油中间体反应合成了一种哌嗪改性聚醚基聚二甲基硅氧烷PPEPS,对其进行了结构表征和应用。结果表明:原料含氢硅油的平均相对分子质量、PPEPS的硅含量对其应用性能有影响。增加原料含氢硅油的平均相对分子质量,提高硅含量,可改善PPEPS的柔软性,而对织物的吸湿性影响不大。

关 键 词:哌嗪改性聚醚基聚二甲基硅氧烷 哌嗪基聚醚硅油 织物柔软剂
文章编号:1000-5811(2004)04-0013-04
修稿时间:2004-02-11

PREPARATION OF PIPERAZINE MODIFIED POLYETHER POLYDIMETHYLSILOXANE AND ITS PERFORMANCE ON FABRICS
AN Qiu-feng,HUANG Liang-xian,LI Lin-sheng,DU Jing-wu. PREPARATION OF PIPERAZINE MODIFIED POLYETHER POLYDIMETHYLSILOXANE AND ITS PERFORMANCE ON FABRICS[J]. Journal of Shaanxi University of Science & Technology(Natural Science Edition), 2004, 22(4): 13-16
Authors:AN Qiu-feng  HUANG Liang-xian  LI Lin-sheng  DU Jing-wu
Abstract:Piperazine modified polyether polydimethylsiloxane (PPEPS) is synthesized by reaction of piperazine with polyether/epoxy silicone, its chemical structure as well as performance has been determined and studied. Application experiment results show that average molecular weight of staple methyl hydrogen silicone and Si content of piperazine modified polyether polysiloxane have effects on PPEPS performance. By increasing the average molecular weight of methyl hydrogen silicone and Si content of PPEPS, softness of the finished fabrics can be improved, but rewettability of the finished fabrics is little influenced.
Keywords:piperazine modified polyether polydimethylsiloxane  piperazine/polyether-group containing silicone  fabric softener
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