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Mechanical and thermal properties of EVA blended with biodegradable ethyl cellulose
Authors:B. G. Girija  R. R. N. Sailaja  Sharmistha Biswas  M. V. Deepthi
Affiliation:1. Department of Chemical Engineering, Indian Institute of Science, Bangalore 560012, India;2. The Energy and Resources Institute (TERI), Southern Regional Centre, Bangalore 560071, India
Abstract:In this study, biodegradable blend of Poly (Ethylene‐co‐Vinyl Acetate) (EVA) and Ethyl Cellulose (EC) were prepared. Ethylene vinyl alcohol (EVOH) copolymer was used as an interfacial compatibilizer to enhance adhesion between EVA and EC. The melt blended compatibilized biocomposites were examined for mechanical and thermal properties as per the ASTM standards. It has been found that the EC has a reinforcing effect on EVA leading to enhanced tensile strength and also impart biodegradability. Thus, a high loading of 50% EC could be added without compromising much on the mechanical properties. Analysis of the tensile data using predictive theories showed an enhanced interaction of the dispersed phase (EC) and the matrix (EVA). The compatibilizing effects of EVOH on these blends were confirmed by the significant improvement in the mechanical properties comparable with neat EVA as also observed by SEM microscopy. The TGA thermograms exhibits two‐stage degradation and as EC content increases, the onset temperature for thermal degradation reduces. © 2009 Wiley Periodicals, Inc. J Appl Polym Sci, 2010
Keywords:EVA  ethyl cellulose  compatibilizer  mechanical and thermal properties  biodegradation
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