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Assessment of polycyclic aromatic hydrocarbons (PAHs) in soil of a Natural Reserve (Isola delle Femmine) (Italy) located in front of a plant for the production of cement
Authors:Santino Orecchio
Affiliation:1. Department of Occupational and Environmental Health, Peking University School of Public Health, Beijing 100871, China;2. Key Laboratory of Molecular Cardiovascular Sciences of Ministry of Education, Peking University, Beijing 100871, China;3. Institute of Earth and Environment, Chinese Academy of Sciences, Xi''an 710061, China;1. Collaborative Innovation Center on Forecast and Evaluation of Meteorological Disasters, Nanjing University of Information Science and Technology, Nanjing 210044, China;2. Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration, Nanjing University of Information Science & Technology, Nanjing 210044, China;1. Environmental Engineering Laboratory, Departament d''Enginyeria Quimica, Universitat Rovira i Virgili, Av. Països Catalans 26, 43007 Tarragona, Catalonia, Spain;2. Institute of Environmental Assessment and Water Research, CSIC, Jordi Girona 18, 08034 Barcelona, Catalonia, Spain;3. Laboratory of Toxicology and Environmental Health, School of Medicine, IISPV, Universitat Rovira i Virgili, Sant Llorenç 21, 43201 Reus, Catalonia, Spain
Abstract:Isola delle Femmine Natural Reserve is a very little isle about 15 km from the centre of Palermo, in front of a plant for the production of cement and about 600 m from coast. In the present research, profiles soil PAHs were obtained for 16 sites within the reserve and for 8 stations on the rural soil taken as reference. ∑PAHs, in the soil of investigated area, ranged from 35 to 545 μg/kg. With the aim to find the origin of PAHs in the soil of Isola delle Femmine, we compare the distribution of single analytes in the investigated area with those of the reference rural area (Monte Raffo Rosso), with those of atmospheric urban particulate collected at Palermo along with reported of emissions of some cement plants. The island's investigated area showed a high amount of 4- and 5-rings PAHs, whereas 3-ring PAHs are present mainly in the emission of cement plants (from literature). The percentage of 3-, 4-, 5- and 6-rings PAHs determined in samples of Isola delle Femmine are similar to those of the reference rural soils and to those of urban atmospheric particulate. Cement plant activity has a negligible weight on the presence of PAHs in the soil of Isola delle Femmine.
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