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Study of preparation and tribological properties of rare earth nanoparticles in lubricating oil
Authors:Rende Liu  Xicheng Wei  Dehua Tao  Yuan Zhao
Affiliation:1. Department of Mechanical Engineering, MEPCO Schlenk Engineering College, Sivakasi 626 005, Tamilnadu, India;2. Department of Mechanical Engineering, V V College of Engineering College, Tisaiyanvilai 627 657, Tamilnadu, India;1. Department of Mechanical Engineering, The University of Akron, Akron, OH 44325, USA;2. Timken Engineered Surfaces Laboratories, The University of Akron, Akron, OH 44325, USA;3. Timken Technology Center, The Timken Company, Canton, OH 44706, USA
Abstract:Surface-modified mixed rare earth nanoparticles are prepared and their tribological performances as lubrication additives are evaluated using a four-ball friction and wear tester. The analytical results show that the average size of the particles is less than 30 nm and they exhibit excellent anti-wear, load-carrying and good friction-reducing capacities in base stock. Auger electron spectroscopy (AES) and X-ray photoelectron spectrometry (XPS) are performed to investigate their tribochemical mechanism and the results indicate that there is a boundary film composed with ferrous oxides, organic acid, rare earth oxides and complex of rare earth metals formed on the rubbed surface. The high concentration of ferrous oxides in the friction surface, which attributes to the oxidation catalysis of nano rare earth particles during the friction process, may be the main reason that leads to their excellent tribological properties.
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