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I2-doped and pyrrole ring-iodinated semi-conducting oligomers of N-vinyl-3-alkyl-2-phenylpyrroles |
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| Authors: | Boris A. Trofimov Marina V. Markova Inna V. Tatarinova Al’bina I. Mikhaleva Lyudmila V. Morozova Ol’ga V. Petrova Lyubov’ N. Sobenina Konstantin B. Petrushenko Tamara I. Vakul'skaya Spartak S. Khutsishvili Galina F. Prozorova |
| Affiliation: | A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of Russian Academy of Sciences, 1 Favorsky St., 664033 Irkutsk, Russian Federation |
| Abstract: | I2-doped and pyrrole ring-iodinated semi-conducting oligomers of N-vinyl-3-alkyl-2-phenylpyrroles have been synthesized by free-radical polymerization of the above monomers (AIBN, 2–5 wt%, 60–80 °C) and further exposure of the oligomers obtained to I2 vapor. The parent oligomers exhibit paramagnetic and fluorescent properties and stable up to 300–370 °C. |
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