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An Equation of State for Fluids by Applying the Tower—Well Potential Model
引用本文:ZengXiangdong ShangDemin 等. An Equation of State for Fluids by Applying the Tower—Well Potential Model[J]. 热科学学报(英文版), 1994, 3(4): 229-235. DOI: 10.1007/BF02653132
作者姓名:ZengXiangdong ShangDemin 等
摘    要:

关 键 词:统计热力学  液态方程  阱势模型

An equation of state for fluids by applying the tower—Well potential model
Xiangdong Zeng,Demin Shang,Jialu Yan. An equation of state for fluids by applying the tower—Well potential model[J]. Journal of Thermal Science, 1994, 3(4): 229-235. DOI: 10.1007/BF02653132
Authors:Xiangdong Zeng  Demin Shang  Jialu Yan
Affiliation:(1) Department of Power Engineering, Harbin Institute of Technology, Harbin, China
Abstract:A simple theoretical equation of state is derived by applying the Tower-Well potential model about the molecular distribution based on the generalized van der Waals partition function. It needs only three molecular parameters which have distinct physical meanings. The resulting equation of state predicts rather well the vapor pressures, saturated liquid volumes, saturated vapor volumes and PVT thermodynamic properties of polar and structurally complex molecules over a wide temperature and pressure range.
Keywords:theoretical equation of state  statistical thermodynamics  tower-well potential model
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