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制备条件对NiMo/γ-Al2O3催化剂上萘加氢生成四氢萘的影响
引用本文:李国峰.制备条件对NiMo/γ-Al2O3催化剂上萘加氢生成四氢萘的影响[J].工业催化,1992,28(10):34-36.
作者姓名:李国峰
作者单位:新疆应用职业技术学院石油与化学工程系,新疆 奎屯 833200
基金项目:国家自然科学基金项目(21163019); 新疆维吾尔自治区奎屯市科技计划项目(201604)
摘    要:采用等体积浸渍法制备加氢催化剂NiMo/γ-Al2O3,在悬浮床上考察不同的制备条件下NiMo/γ-Al2O3对萘加氢生成四氢萘的影响。结果表明,催化剂的制备条件对加氢活性有显著的影响,NiMo/γ-Al2O3催化剂的最佳制备条件为共浸渍法负载金属组分Ni和Mo,在500 ℃的温度下焙烧4 h。此条件下制备的催化剂上四氢萘的选择性高达95.2%。

关 键 词:催化剂工程  浸渍法  加氢催化剂  四氢萘  NiMo/γ-Al2O3  

Effect of preparation conditions on the hydrogenation of naphthalene totetralin over NiMo/γ-Al2 Al2O3catalyst
Li Guofeng.Effect of preparation conditions on the hydrogenation of naphthalene totetralin over NiMo/γ-Al2 Al2O3catalyst[J].Industrial Catalysis,1992,28(10):34-36.
Authors:Li Guofeng
Affiliation:Department of Petro and Chemical Engineering,Xinjiang Career Technical College,Kuitun 833200,Xinjiang,China
Abstract:NiMo/γ-Al2O3 catalyst was prepared by equal volume impregnation.The effects on the hydrogenation of naphthalene to tetralin of NiMo/γ-Al2 O3prepared by different conditions were investigated on a slurry-phase hydrocracking reactor.The results show that the catalysts prepared under different conditions have a significant influence on the hydrogenation activity.The optimal preparation conditions of NiMo/γ-Al2O3 catalyst are as follows:the metal components Ni and Mo are supported by the co-impregnation method,and the calcination is performed at 500 ℃ for 4 h,under this condition,the selectivity of tetralin is up to 95.2%.
Keywords:catalyst engineering  impregnation method  hydrogenation catalyst  tetralin  NiMo/γ-Al2O3  
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