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Magnetocaloric effect of La0.8Ce0.2Fe11.4−xMnxSi1.6 compounds
Authors:Zhiping Lin  Shandong Li  Meimei Liu  Jenq-Gong Duh  Ken Peng  Xingyu Mao
Affiliation:1. Department of Physics, Fujian Normal University, Fuzhou 350007, China;2. Department of Materials Science and Engineering, National Tsing Hua University, Hsinchu 30013, Taiwan;3. National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093, China;4. Ningbo Institute of Material Technology & Engineering, Chinese Academy of Sciences, Ningbo 315201, China;5. College of Materials Science and Engineering, Hunan University, Changsha 410082, China;6. Institute of Science, Jimei University, Xiamen 361000, China;1. Institute for Metallic Materials, IFW Dresden, P.O. Box 270116, D-01171 Dresden, Germany;2. Institute for Materials Science, TU Dresden, Helmholtzstrasse 7, 01069 Dresden, Germany;3. Mechanical Engineering Department, Federal University of Santa Catarina, CEP 88040-900, Florianópolis, Brazil;4. Materials Science, TU Darmstadt, Alarich-Weiss-Str. 16, 64287 Darmstadt, Germany;5. Institute for Complex Materials, IFW Dresden, P.O. Box 270116, D-01171 Dresden, Germany;6. Key Laboratory of Magnetic Materials and Devices, Ningbo Institute of Material Technology and Engineering, CAS, Ningbo 315201, People’s Republic of China;7. Fraunhofer IWKS, Project Group for Material Cycles and Resource Strategy, 63457 Hanau, Germany;1. School of Materials Science and Engineering, Sichuan University, Chengdu 610065, PR China;2. Department of Physics and Electronic Informational Engineering, Neijiang Teachers College, Neijiang 641002, PR China;1. IFW Dresden, Institute for Complex Materials, PO Box 270116, D-01171 Dresden, Germany;2. TU Darmstadt, Materials Science, Alarich-Weiss-Str. 16, D-64287 Darmstadt, Germany;3. TU Dresden, Institute of Materials Science, Helmholtzstr. 7, D-01069 Dresden, Germany;1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China;2. Baotou Research Institute of Rare Earths, Baotou 014030, China;3. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;4. Sanqiaohui (Foshan) New Materials Co., Ltd., Foshan 528253, China;5. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;6. Singapore-HUJ Alliance for Research and Enterprise (SHARE), Nanomaterials for Energy and Energy-Water Nexus (NEW), Campus for Research Excellence and Technological Enterprise (CREATE), Singapore 138602, Singapore;1. School of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China;2. Baotou Research Institute of Rare Earths, Baotou 014030, China;3. School of Materials Science and Engineering, University of Science and Technology Beijing, Beijing 100083, China;4. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;5. Singapore-HUJ Alliance for Research and Enterprise (SHARE), Nanomaterials for Energy and Energy-Water Nexus (NEW), Campus for Research Excellence and Technological Enterprise (CREATE), Singapore 138602, Singapore
Abstract:The effect of Mn addition on the magnetocaloric effect (MCE) of the La0.8Ce0.2Fe11.4?xMnxSi1.6 (x = 0.0, 0.1, 0.2, 0.3) compounds was investigated. It was revealed that the transition temperatures of the compounds are sensitive to Mn composition. The temperatures are shifted from 177 to 121 K for Mn composition from 0.0 to 0.3. Moreover, thermal lag and magnetic hysteresis loss of the compounds are reduced largely due to Mn addition. A good MCE with a large and almost constant refrigerant capacity in a large temperature span over 50 K was achieved in the investigated compounds. The investigated compounds are promising magnetic entropy change materials.
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