Anion-directed assembly of two novel cadmium(II) complexes constructed by 2,2′-(1,4-butanediyl)bis(1H-benzimidazole) ligand |
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| Authors: | Yong Wang Hong-Bin Xu Zhong-Min Su Kui-Zhan Shao Ya-Hui Zhao Hong-Peng Cui Ya-Qian Lan Xiang-Rong Hao |
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| Affiliation: | aInstitute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, PR China |
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| Abstract: | Depending on the different coordinated anions used, reaction of Cd(II) salt with 2,2′-(1,4-butanediyl)bis(1H-benzimidazole) results in the formation of two coordination polymers: a 1D chain {Cd(H2C4BIm)Cl2] · (H2C4BIm)}n (1), and a 2D sheet Cd(HC4BIm)(NCS)]n (2) which features distorted 4.82 topology (H2C4BIm = 2,2′-(1,4-butanediyl)bis(1H-benzimidazole)). The fluorescence properties for both the complexes have been studied. |
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| Keywords: | Hydrothermal synthesis Crystal structure 4 82 Topology Fluorescence |
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