Conduction mechanism of metal-free phthalocyanine single crystals as a function of temperature

Metal-free phthalocyanine (H₂Pc) single crystals grown by vacuum sublimation were investigated for their conductivity (both in dark and light). The investigations consisted of dark- and photo-current variations with (i) applied electric field and (ii) temperature. The applied electric field ranged from 0·8 kV/cm to 6 kV/cm. The temperature range was from 300°K to around 570°K. The crystals were found to be photoconductive. Based on activation energies calculated from photoconductivity due to temperature dependence, an energy level scheme for H₂Pc single crystals is proposed. The model consists of two trapping levels within the forbidden gap — one at 0·4 eV below the conduction band edge from which electrons are thermally excited into the conduction band and the other acts as recombination centre at 0·3 eV above the valence band edge. The band gap is calculated to be 1·4 eV. Comparative study of the proposed model with that of earlier investigations on the same crystals of the H₂Pc is in good agreement, thereby indicating that H₂Pc is thermally stable even at relatively higher temperature as semiconductor.