| Thermal decomposition mechanism and non-isothermal kinetics of the polyoxometalate of ciprofloxacin with 12-tungstoboric acid |
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| 引用本文： | WANG Dunjia,FANG Zhengdong,and HAN DeyanDepartment of Chemistry and Environmental Engineering,Hubei Normal University,Huangshi 435002,China. Thermal decomposition mechanism and non-isothermal kinetics of the polyoxometalate of ciprofloxacin with 12-tungstoboric acid[J]. 稀有金属(英文版), 2005, 24(1): 15-21 |
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| 作者姓名： | WANG Dunjia FANG Zhengdong and HAN DeyanDepartment of Chemistry and Environmental Engineering Hubei Normal University Huangshi 435002 China |
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| 作者单位： | WANG Dunjia，FANG Zhengdong，and HAN DeyanDepartment of Chemistry and Environmental Engineering，Hubei Normal University，Huangshi 435002，China |
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| 基金项目： | ThisprojectwasfinanciallysupportedbytheNaturalScienceFoundationofHubeiProvince,China(No.2003ABA062)theNaturalScienceFoundationoftheEducationalCommissionofHubeiProvince,China(No.2003A001). |
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| 摘 要： | The polyoxometalate complex (CPFX·HCl)4H5BW12O40·12H2O was prepared in aqueous solution for the first time, and characterized by elemental analysis, IR spectrum, and TG-DTG. The TG-DTG curves showed that its thermal decomposition was a four-step process
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Thermal decomposition mechanism and non-isothermal kinetics of the polyoxometalate of ciprofloxacin with 12-tungstoboric acid |
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| WANG Dunjia,FANG Zhengdong,HAN Deyan. Thermal decomposition mechanism and non-isothermal kinetics of the polyoxometalate of ciprofloxacin with 12-tungstoboric acid[J]. Rare Metals, 2005, 24(1): 15-21 |
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| Authors: | WANG Dunjia FANG Zhengdong HAN Deyan |
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| Affiliation: | Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, China |
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| Abstract: | The polyoxometalate complex (CPFX·HCl)4H5BW12O40·12H2O was prepared in aqueous solution for the first time, and characterized by elemental analysis, IR spectrum, and TG-DTG. The TG-DTG curves showed that its thermal decomposition was a our-step process consisting of the simultaneous collapse of Keggin anion. The intermediate and residue of the decomposition were identified by mean of TG-DTG, IR, and XRD technique. The non-isothermal kinetic data were analyzed by the Achar method and Coats-Redfern method. The apparent activation energy (E) and the pre-exponential factor (ln A) of each decomposition were obtained. The most probable thermal decomposition reaction mechanisms were proposed by comparison of the kinetic parameters. The kinetic equation for both the second stage and the third stage can be expressed as dα/dt = Ae-EIRT·(1 - α)2, and the fourth stage dα/dt = Ae-EIRT·( 1 - α). And their athematic expressions of the kinetic compensation effects of thermal decomposition reaction were also determined. |
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| Keywords: | physical chemistry thermal decomposition mechanism non-isothermal kinetics TG-DTG polyoxometalate complex ciprofloxacin tungstoborate |
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