| 新型耐热环氧单体的合成及性质研究 |
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| 引用本文： | 林尤谊,龚福春,孙蓉,张国平.新型耐热环氧单体的合成及性质研究[J].合成材料老化与应用,2013(4):1-5. |
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| 作者姓名： | 林尤谊 龚福春 孙蓉 张国平 |
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| 作者单位： | 长沙理工大学化学与生物工程学院;中国科学院深圳先进技术研究院集成所先进材料中心 |
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| 基金项目： | 国家自然科学基金(21201175);广东省引进创新科研团队计划资助(2011D052);深圳市战略性新兴产业发展专项资金(JCYJ20120615140007998) |
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| 摘 要： | 报道了一种含萘芳香酯型环氧单体二（4-（2，3-环氧丙氧基）苯甲酸）．2，7-萘4，4-二酯（P4）的合成及性质研究。利用FT-IR、1HNMR、质谱等分析测试方法对P4目标化合物的结构进行了表征。并用4，4．二氨基二苯基砜（DDS）和4，4-二氨基二苯基甲烷（DDM）两种芳香二胺固化剂对P4进行非等温固化研究。由结果可知，DDM／P4的固化峰温度为140℃，DDS／P4的固化峰温度为210℃，DDM能显著降低P4的固化温度。最后，通过对P4／DDM和环氧E20／DDM这两种固化物的热失重研究表明P4／DDM固化物具有较高的热稳定性。
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| 关 键 词： | 萘，环氧单体，合成，固化 |
Investigation on the Synthesis and Properties of Novel Heat-resistant Epoxy Monomer |
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| LIN You-yi;GONG Fu-chun;SUN Rong;ZHANG Guo-ping.Investigation on the Synthesis and Properties of Novel Heat-resistant Epoxy Monomer[J].Synthetic Materials Aging and Application,2013(4):1-5. |
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| Authors: | LIN You-yi;GONG Fu-chun;SUN Rong;ZHANG Guo-ping |
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| Affiliation: | LIN You-yi;GONG Fu-chun;SUN Rong;ZHANG Guo-ping;Department of Chemical and Biological Engineering,Changsha University of Science and Technology;Shenzhen Institute of Advanced Technology,Chinese Academy of Sciences; |
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| Abstract: | The synthesis and properties of a novel epoxy mornor naphthalene-4,4＇-diylbis（4-（ oxiran-2-ylme- thoxy） benzoate） were reported by this work. The molecular structure were characterized by Fr-IR, 1H NMR, and mass spectra. Two curing agents,4,4-diaminodiphenylsulfon （DDS） and 4,4-Diaminodiphenyl methane （ DDM ）, were chosen to investigate the curing behavior of P4/aromatic diamine by means of nonisothermal DSC. It can be seen from results that the curing peak temperature of P4/DDM is 140℃ and that of P4/DDS is 210℃. Comparing with DDS, DDM can decrease the curing temperature of P4. At last, the thermogravimetry analysis of P4/DDM com- posites and E20/DDM composites were also investigated. The results showed that the P4/DDM composites presented higher thermal stability. |
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| Keywords: | naphthalene epoxy monomer synthesis curing |
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