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热复分解法制备硫酸钾的研究
引用本文:陈联梅,康泰然,王中华,陈天朗.热复分解法制备硫酸钾的研究[J].云南化工,2006,33(4):33-35,53.
作者姓名:陈联梅  康泰然  王中华  陈天朗
作者单位:1. 西华师范大学,化学学院,四川,南充,637002
2. 四川大学,化学学院,四川,成都,610064
摘    要:利用热复分解法来制备硫酸钾。将硫酸铵和氯化钾按一定比例充分混合,在高于340℃下反应1~2 h。反应过程中副产物氯化铵(NH4C l)升华分离出去,从而留下主产物硫酸钾(K2SO4)。由于主产物中氯的含量较高,必须想法降低其氯含量,达到无氯钾肥的合格标准。

关 键 词:硫酸钾  硫酸铵  氯化钾  复分解法
文章编号:1004-275X(2006)04-0033-03
收稿时间:2006-03-22
修稿时间:2006-03-22

Investigation on the Preparation of Potassium Sulfate by Thermal Metathetical Reaction
CHEN Lian-mei,KANG Tai-ran,WANG Zhong-hua,CHEN Tian-lang.Investigation on the Preparation of Potassium Sulfate by Thermal Metathetical Reaction[J].Yunnan Chemical Technology,2006,33(4):33-35,53.
Authors:CHEN Lian-mei  KANG Tai-ran  WANG Zhong-hua  CHEN Tian-lang
Affiliation:1. School of Chemistry and Chemical Engineering, China West Normal University, Nanehong 637000, China; 2. School of Chemistry, Siehuan University, Chengdu 610064, China
Abstract:The preparation of potassium sulfate by thermal metathetical reaction was investigated by heating the mixture of(NH_4)_2SO_4 with KCl at 340 ℃ for 1~2h.The by-product NH_4Cl was removed away by sublimation and the main-product K_2SO_4 was left.
Keywords:potassium sulfate  ammonium sulfate  potassium chloride  metatheticaI reaction
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