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光引发合成两性离子型聚丙烯酰胺的影响因素
引用本文:马帅,聂容春,王允雨,孙银宇. 光引发合成两性离子型聚丙烯酰胺的影响因素[J]. 精细石油化工, 2011, 28(6): 13-16
作者姓名:马帅  聂容春  王允雨  孙银宇
作者单位:安徽理工大学化学工程学院,安徽淮南,232001
摘    要:实验以紫外光引发聚合方式,研究了丙烯酸钠(AANa),甲基丙烯酰氧乙基三甲基氯化铵(DMC),丙烯酰胺(AM)共聚合成两性离子型聚丙烯酰胺(AmPAM).最佳工艺条件为:n(AM)∶n(DMC)∶n(AANa)=1∶0.12∶ 0.65,单体总质量分数为40%,光引发剂质量分数为0.8%,pH=6.5,反应温度为40℃...

关 键 词:两性离子型聚丙烯酰胺  光引发  影响因素

INFLUENCING FACTORS IN PHOTO-INITIATION SYNTHESIS OF POLYACRYLAMIDE
Ma Shuai,Nie Rongchun,Wang Yunyu,Sun Yinyu. INFLUENCING FACTORS IN PHOTO-INITIATION SYNTHESIS OF POLYACRYLAMIDE[J]. Speciality Petrochemicals, 2011, 28(6): 13-16
Authors:Ma Shuai  Nie Rongchun  Wang Yunyu  Sun Yinyu
Abstract:Amphoteric polyacrylamide was synthesized by UV photoinitiation with methyl isopropyl trimethylammonium chloride,sodium acrylate and acrylamide as the monomers.Under the following optimal reaction conditions,the molar ratio of AM,DMC,AANa of 1∶0.12∶0.65,the total concentration of monomers of 40%,the initiator dosage of 0.8%,pH 6.5 and reaction temperature 40 ℃,the intrinsic viscosity of the product was 806 mL/g.The structure was confirmed by infrared resonance spectrum.
Keywords:mphoteric polycrylamide  UV photoinitiation  influencing factor
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