| 电合成苯甲醛及其衍生物的研究进展 |
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| 引用本文： | 付忠超,李琪,乔庆东. 电合成苯甲醛及其衍生物的研究进展[J]. 精细化工中间体, 2011, 41(3): 15-18 |
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| 作者姓名： | 付忠超 李琪 乔庆东 |
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| 作者单位： | 辽宁石油化工大学石油化工学院,辽宁抚顺,113001 |
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| 摘 要： | 苯甲醛及其衍生物是一类非常重要的有机化工原料和反应中间体。采用电合成法制备苯甲醛及其衍生物比用传统的有机合成法有明显优势,具有环保、高效和节能等优点。综述了电合成苯甲醛及其衍生物的方法,包括直接电解氧化法、间接电氧化法、电解还原法、牺牲阳极法。讨论了间接电合成苯甲醛的影响因素,如电解媒质,电极和反应条件。最后归纳了几种重要的表征方法,包括极谱法、气相色谱法、紫外分光光度法和电位滴定法等。
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| 关 键 词： | 苯甲醛 电合成 Mn3+ |
Review on the Electrosynthesis of Benzaldehyde and Its Derivatives |
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| FU Zhong-chao,LI Qi,QIAO Qing-dong. Review on the Electrosynthesis of Benzaldehyde and Its Derivatives[J]. Fine Chemical Intermediates, 2011, 41(3): 15-18 |
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| Authors: | FU Zhong-chao LI Qi QIAO Qing-dong |
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| Affiliation: | (School of Petrochemical Engineering,Liaoning Petrochemical University,Fushun 113001,China) |
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| Abstract: | Benzaldehyde and its derivatives have been widely used in organic synthesis.Compared with conventional synthesis,the electrosynthesis of benzaldehyde and its derivatives has many advantages,such as environmentally friendly,high efficiency and energy saving.Various electrosynthesis methods and the corresponding reaction conditions and characterization of the products were reviewed. |
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| Keywords: | benzaldehyde electrosynthesis Mn3+ |
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