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液相法控制合成文石和方解石
引用本文:李庆,林华,胡金柱,王卫星,YAN Ping.液相法控制合成文石和方解石[J].功能材料,2006,37(3):487-491.
作者姓名:李庆  林华  胡金柱  王卫星  YAN Ping
作者单位:西南大学材料科学与工程学院,重庆,400715;School of Materials Science and Engineering, Southwest China University, Chongqing 400715, China
基金项目:Financial support from the Key Project of Chinese Ministry of Education (105144)
摘    要:用简便的水热法制备出菱形、针状和树状的碳酸钙晶体,不需任何添加剂,也不需要对pH值进行控制.用XRD、SEM、FT-IR和TGA-DTA技术对产物的形貌、结构特征和热力学稳定性进行了表征.对实验条件的系统研究发现,通过控制反应物的浓度,即可简便地获得多种晶型和形貌的碳酸钙.

关 键 词:无机化合物  化学反应  晶体生长  化学法
文章编号:1001-9731(2006)03-0487-05
收稿时间:2005-04-19
修稿时间:2005-07-12

Control synthesis of aragonite and calcite in aqueous solution
LI Qing,LIN Hua,HU Jin-zhu,WANG Wei-xing,YAN Ping.Control synthesis of aragonite and calcite in aqueous solution[J].Journal of Functional Materials,2006,37(3):487-491.
Authors:LI Qing  LIN Hua  HU Jin-zhu  WANG Wei-xing  YAN Ping
Affiliation:School of Materials Science and Engineering, Southwest China University, Chongqing 400715, China
Abstract:CaCO3 polymorphs with rhombohedra, needle-, tree-like morphologies have been synthesized by a convenient hydrothermal reaction with the absence of additives or elaborating pH control. XRD, SEM, FT-IR and TGA-DTA techniques were used to characterize the structural features and thermal behavior of the experimental products. The experimental conditions were explored systematically and it was found that polymorphs with manifold morphologies of CaCO3 could be conveniently synthesized by controlling the concentration of reactants.
Keywords:Inorganic compounds  chemical synthesis  crystal growth  chemical techniques
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