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Enneahalodimetallates(III) of rare earth elements with the hexagonal Cs3Tl2Cl9-(h)6-type structure
Authors:Gerd Meyer  Andreas Schönemund
Affiliation:Institut für Anorganische und Analytische Chemie I Universität Giessen, D-6300 Giessen, West Germany
Abstract:Enneachloro- and bromodimetallates(III) of rare earth elements Cs3RE2X9, of which only a few have been observed in a phase diagram, were prepared and investigated by Guinier-Simon X-ray technique. Except for Cs3Sc2Br9 (isotypic with Cs3Cr2Cl9) they - for RE = Sc, Y,Ho-Lu, X = Cl as well as RE = Sc, Sm-Lu, X = Br - crystallize with the Cs3Tl2Cl9-type structure.
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