| KOH／SBA-15负载型固体碱催化剂的合成、表征及催化性能 |
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| 引用本文： | 朱明明,万庆宇,宋芊慧,蔡天凤,李会鹏,赵华.KOH／SBA-15负载型固体碱催化剂的合成、表征及催化性能[J].化工科技,2013,21(1):9-11. |
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| 作者姓名： | 朱明明 万庆宇 宋芊慧 蔡天凤 李会鹏 赵华 |
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| 作者单位： | 辽宁石油化工大学石油化工学院,辽宁抚顺,113001 |
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| 基金项目： | 辽宁省博士启动基金资助项目 |
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| 摘 要： | 采用后合成法制备出固体碱催化剂KOH／SBA-15，利用X射线衍射法（XRD）、N2吸附-脱附（BET）、透射电镜（TEM）、化学吸附剂表面碱性测定（COz—TPD）等对其进行表征。考察了其在大豆油酯交换反应制备生物柴油中的催化性能。结果表明，在相同反应条件下，与CaO／SBA-15和MgO／SBA-15相比，KOH／SBA-15在催化活性和孔扩散上都具有较大的优越性，催化制备生物柴油产率最高（83．56％）。
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| 关 键 词： | KOH SBA-15 固体碱催化剂 表征 催化性能 |
Synthesis, characterization and catalytic performance of supported solid base catalyst of KOH/SBA-15 |
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| Zhu Mingming
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Wan Qingyu
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Song Qianhui
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Cai Tianfeng
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Li Huipeng
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Zhao Hua.Synthesis, characterization and catalytic performance of supported solid base catalyst of KOH/SBA-15[J].Science & Technology In Chemical Industry,2013,21(1):9-11. |
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| Authors: | Zhu Mingming Wan Qingyu Song Qianhui Cai Tianfeng Li Huipeng Zhao Hua |
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| Affiliation: | (School of Petrochemical Engineering,Liaoning Shihua University,Fushun 113001,China) |
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| Abstract: | SBA-15 was modified by introducing an active component by post-synthetic method for pre- paring a solid base catalyst KOH/SBA-15. Characterization was carried out by XRD, BET, TEM and CO2-TDP to understand the nature. KOH/SBA-15 catalytic performance on transesterification to pro- duce biodiesel from soybean oil was studied. In the same reaction conditions, compared to CaO/SBA-15 and MgO/SBA-15, （15%）KOH/SBA-15 showed the highest yield of biodiesel, due to its favorable su- periority on catalytic activity and pore diffusion. |
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| Keywords: | KOH/SBA-15 Solid base catalyst Characterization Catalytic performance |
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