Preparation and characterization of high loading porous crosslinked poly(vinyl alcohol) resins |
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Authors: | Ying Wan Zheng Wang XX Zhu |
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Affiliation: | a Département de Chimie, Université de Montréal, C.P. 6128, Succursale Centre-ville, Montréal, Que., Canada H3C 3J7 b State Key Laboratory of Functional Polymer Materials for Adsorption and Separation, Institute of Polymer Chemistry, Nankai University, Tianjin 300071, People's Republic of China |
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Abstract: | Porous crosslinked poly(vinyl alcohol) resin beads have been prepared by a two-step pathway involving a pre-crosslinking reaction followed by a reverse suspension crosslinking reaction with epichlorohydrin as crosslinker. The reaction conditions have been optimized for the two steps in order to obtain resins with various pores sizes. The crosslinking density of these resins was calculated from their swelling properties by a modified Flory equation. High loading of hydroxyl groups is one of the important characteristics of these resins (attaining ca. 17 mmol/g). The porosity, pore volume, pore structure and the swelling behavior in water of these resins have been studied. |
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Keywords: | Polymer resin Poly(vinyl alcohol) High loading resins |
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