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The effects of ruthenium additions on tensile deformation mechanisms of single crystal superalloys at different temperatures
Affiliation:1. School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai 200240, PR China;2. Shanghai Key Laboratory of High Temperature Materials and Precision Forming, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai 200240, PR China;3. Gas Turbine Research Institute, Shanghai Jiao Tong University, 800 Dong Chuan Road, Shanghai 200240, PR China;1. Superalloys Division, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;2. Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China;1. State Key Laboratory for Advanced Metals and Materials, University of Science and Technology Beijing, Beijing 100083, China;2. Department of Materials Science and Engineering, University of Michigan, Ann Arbor, MI 48109, USA;3. Beijing Key Laboratory of Special Melting and Reparation of High-End Metal Materials, University of Science and Technology Beijing, Beijing 100083, China;1. Superalloys Division, Institute of Metal Research, Chinese Academy of Sciences, 72 Wenhua Road, Shenyang 110016, China;2. High Temperature Materials Research Group, Korea Institute of Materials Science, 797 Changwondaero, Changwon, Gyeongnam 641-831, Republic of Korea;1. Key Laboratory for Liquid-Solid Structural Evolution & Processing of Materials, Ministry of Education, Shandong University, Jinan 250061, China;2. State Key Laboratory for Advanced Metals and Material, University of Science and Technology Beijing, Beijing 100083, China;3. National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China;1. Environment and Energy Materials Division, National Institute for Materials Science, Sengen 1-2-1, Tsukuba 305-0047, Japan;2. High Temperature Materials Unit, National Institute for Materials Science, Sengen 1-2-1, Tsukuba 305-0047, Japan
Abstract:The tensile behavior of two experimental nickel-base single crystal superalloys has been studied from room temperature to 1100 °C. Emphasis is placed on elucidating the effects of ruthenium (Ru) additions on the deformation mechanisms using transmission electron microscopy (TEM). Furthermore, the partitioning behavior of the alloy elements between the γ and γ′ phases for both experimental alloys has been studied using three-dimensional atom probe (3DAP). Detailed analysis demonstrates that at low and medium temperature ranges, the stacking faults present in the γ matrix of the 3Ru alloy but no trace of stacking fault in the γ matrix of the 0Ru alloy have been observed; during high temperature range, as a result of Ru additions, the γ/γ′ interfacial dislocation space of the 3Ru alloy is smaller than that of the 0Ru alloy due to further decreasing the lattice misfit. Apart from that, Ru additions result in more Re partitioning to the γ′ phase, and thus the solution strengthening for the γ phase is decreasing. Thus, during tests below and at the temperature corresponding to the peak strength, the yield strength of the 3Ru alloy is lower than that of the 0Ru alloy. At last, in the light of the TEM observations, the changing trends of the stacking fault energy in the γ matrix and the transformation points (the temperature related to the stacking faults formation) for the two experimental alloys have been drawn. The temperature range of the stacking faults formation in the γ matrix is expanded after Ru additions. The energy conditions of the stacking faults formation of the 0Ru and 3Ru alloys have been analyzed in detail. The changing of lattice misfit with temperature can be considered as one of the principal reasons for the stacking faults formation.
Keywords:Tensile behavior  Deformation mechanisms  Yield strength  Stacking fault energy  Ru
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