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Hierarchical Self‐Organization of Nanomaterials into Two‐Dimensional Arrays Using Functional Polymer Scaffold
Authors:Muhammad Hanafiah Nurmawati  Parayil Kumaran Ajikumar  Ravindranath Renu  Suresh Valiyaveettil
Abstract:Fabrication of two and three‐dimensional nanostructures requires the development of new methodologies for the assembly of molecular/macromolecular objects on substrates in predetermined arrangements. Templated self‐assembly approach is a powerful strategy for the creation of materials from assembly of molecular components or nanoparticles. The present study describes the development of a facile, template directed self‐assembly of (metal/organic) nanomaterials into periodic micro‐ and nanostructures. The positioning and the organization of nanomaterials into spatially well‐defined arrays were achieved using an amphiphilic conjugated polymer‐aided, self‐organization process. Arrays of honeycomb patterns formed from conjugated C12PPPOH film with homogenous distribution of metal/organic nanomaterials. Our approach offers a straightforward and inexpensive method of preparation for hybrid thin films without environmentally controlled chambers or sophisticated instruments as compared to multistep micro‐fabrication techniques.
Keywords:hybrid materials  micro‐/nanostructuring  nanomaterials  poly(p‐phenylene)  self‐assembly
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