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A nickel molybdenite cathode for the hydrogen evolution reaction in alkaline media
Authors:L. B. Albertini  A. C. D. Angelo  E. R. Gonzalez
Affiliation:(1) Instituto de Fisica e Quimica de Sao Carlos/USP, C.P. 369, 13560 Sao Carlos, SP, Brazil;(2) Present address: Departamento de Quimica, UNESP, Bauru, C.P. 473, 17100 Bauru, Sao Paulo, Brazil
Abstract:The characteristics and mechanism of the hydrogen evolution reaction on a nickel sulphide electrode incorporating molybdenite particles are described. At 25°C the overpotential for the reaction is 300 mV lower than that of the mild steel cathodes used in unipolar electrolysers. The material shows good stability under long term operation.
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