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表面活性剂对掺铁纳米TiO_2光催化性能的影响
引用本文:李玉胶,赵淑梅,朱春城.表面活性剂对掺铁纳米TiO_2光催化性能的影响[J].化学工程师,2010,24(3):7-9,14.
作者姓名:李玉胶  赵淑梅  朱春城
作者单位:1. 哈尔滨师范大学,化学化工学院,黑龙江,哈尔滨,150025
2. 黑龙江省教育学院,黑龙江,哈尔滨,150001
基金项目:黑龙江省自然科学基金项目(E2007-09);;哈尔滨师范大学国家预研基金资助
摘    要:以钛酸丁酯为原料,采用溶胶-凝胶法制备了纳米TiO2粉末,在其中添加了过渡金属元素铁,并在表面包覆少量的表面活性剂(CTAB)。经紫外光照射后,通过紫外-可见分光光度计测量了光催化降解反应后降解率的变化,探讨了在两者共同作用下的TiO2粉体的光催化活性。实验结果表明:在样品中掺杂一定量的Fe3+并包覆表面活性剂(CTAB),TiO2的结构上并没有发生改变;在Fe3+和CTAB的作用下的纳米TiO2的光催化活性有了显著地提高。

关 键 词:溶胶凝胶  TiO2  CTAB  光催化性能

Effect of surfactants on photocatalytic properties of nano-TiO2 doped with Fe3+
LI Yu-jiao,ZHAO Shu-mei,ZHU Chun-cheng.Effect of surfactants on photocatalytic properties of nano-TiO2 doped with Fe3+[J].Chemical Engineer,2010,24(3):7-9,14.
Authors:LI Yu-jiao  ZHAO Shu-mei  ZHU Chun-cheng
Affiliation:1.Institute of Chemistry and Chemical Engineering;Harbin Normal University;Harbin 150025;China;2.Chemistry Department of Heilongjiang College of Education;Harbin 150001;China
Abstract:Nano-TiO2 powder was prepared by sol-gel route.We used the butyl titanate as raw materials,doped with iron which is one of the transition metal elements,and coating a small amount of hexadecyl trimethyl ammonium bromide(CTAB)as surfactants.After irradiation of UV measurement of the photocatalytic degradation re-action rate of degradation of Change carry out by UV-Vis,the photo-catalytic activity of TiO2 powder under these effects are disscused.The experimental results show that a certain amount of surfactan...
Keywords:sol-gel  TiO2  CTAB  photocatalytic properties  
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