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Effects of Spark Plasma Sintering Temperature on Thermoelectric Properties of Higher Manganese Silicide
Authors:Tae-Ho An  Soon-Mok Choi  Won-Seon Seo  Chan Park  Il-Ho Kim  Sun-Uk Kim
Affiliation:1. Green Ceramics Division, Korea Institute of Ceramic Engineering and Technology (KICET), Seoul, 233-5, Republic of Korea
2. Department of Materials Science and Engineering, Seoul National University, 599, Gwanangno, Gwanak-gu,, Seoul, 151-744, Republic of Korea
3. School of Energy, Materials and Chemical Engineering, Korea University of Technology and Education, 1600 Chungjeolno, Chungnam, Cheonan, 330-708, Republic of Korea
4. Department of Material Science and Engineering, Korea National University of Transportation, Chung-buk, Chungju, 380-702, Republic of Korea
5. Functional Materials Research Department, Research Institute of Industrial Science and Technology (RIST), Pohang, 790-330, Republic of Korea
Abstract:Higher manganese silicide (HMS) is a promising p-type thermoelectric material. HMS samples were synthesized by a vacuum induction melting process and sintered by spark plasma sintering (SPS) at various temperatures to obtain a single phase of HMS and investigate the effect of the SPS temperature on the thermoelectric properties. A single phase of HMS was obtained, and the appearance and the amount of Mn2O3 and MnSi as secondary phases could be controlled via the SPS temperature. The effects of the SPS temperature on the electrical conductivity and Seebeck coefficient of the HMS samples were investigated. The changes in the electrical conductivity and Seebeck coefficient were attributed to changes in the density and the amount of Mn2O3 secondary phase.
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