| 硫酸镓催化合成丙酸正丁酯 |
| |
| 引用本文： | 陈丹云 蔡永伟. 硫酸镓催化合成丙酸正丁酯[J]. 食品与药品, 2007, 9(10A): 9-10 |
| |
| 作者姓名： | 陈丹云 蔡永伟 |
| |
| 作者单位： | 河南大学化学化工学院,河南开封475001 |
| |
| 基金项目： | 河南省教育厅自然科学研究项目（2004601042）;河南省教育厅自然科学计划项目（200510475015）. |
| |
| 摘 要： | 目的研究硫酸镓在合成丙酸正丁酯工艺中的催化性能。方法考察硫酸镓用量、醇酸物质的量比、反应时间及催化剂重复使用次数等因素对收率的影响。结果硫酸镓催化活性高，易分离回收，操作简单，后处理方便，重复使用性良好。最佳反应条件下收率为86．03％。结论硫酸镓是合成丙酸正丁酯的良好催化剂。
|
| 关 键 词： | 丙酸正丁酯 硫酸镓 催化 合成 |
| 文章编号： | 1672-979X（2007）10-0009-02 |
| 修稿时间： | 2007-07-02 |
Synthesis of n-Butyl Propionate Catalyzed by Gallium Sulfate |
| |
| CHEN Dan-yun, CAI Yong-wei. Synthesis of n-Butyl Propionate Catalyzed by Gallium Sulfate[J]. Food and Drug, 2007, 9(10A): 9-10 |
| |
| Authors: | CHEN Dan-yun CAI Yong-wei |
| |
| Affiliation: | College of Chemistry and Chemical Engineering, Henan University, Kaifeng 475001, China |
| |
| Abstract: | Objective To study the catalytic activity of gallium sulfate in the synthesis of n-butyl propionate. Methods The effects of amount of gallium sulfate, molar ratio of alcohol to acid, reaction time and repeated times of catalyst on the yield of n-butyl propionate were investigated. Results Gallium sulfate had high catalytic activity and could be recovered easily, operated simply, post-treated conveniently and used repeatedly. Under the best conditions, the yield of n-butyl propionate could reach 86.03%. Conclusion Gallium sulfate is an excellent catalyst for the synthesis of n-butyl propionate. |
| |
| Keywords: | n-butyl propionate gallium sulfate catalysis synthesis |
| 本文献已被 维普 等数据库收录！ |
