In situ polymerization of bio‐based thermosetting polyurethane/graphene oxide nanocomposites |
| |
| Authors: | Jing Zhang Chaoqun Zhang Samy A Madbouly |
| |
| Affiliation: | 1. Department of Materials Science and Engineering, Iowa State University, Ames,, Iowa;2. Department of Corrosion Prevention and Polymer Materials, College of Materials Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang, China;3. Department of Chemistry, Faculty of Science, Cairo University, Orman‐Giza, Egypt |
| |
| Abstract: | Novel bio‐based polyurethane/graphene oxide (GO) nanocomposites have been successfully synthesized from biorenewable epoxidized soybean‐castor oil fatty acid‐based polyols with considerable improvement in mechanical and thermal properties. The GO was synthesized via a modified pressurized oxidation method, and was investigated using Raman spectra, AFM and XPS, respectively. The toughening mechanism of GO in the bio‐based polyurethane matrix was explored. The elongation at break and toughness of polyurethane were increased by 1.3 and 0.8 times with incorporation of 0.4 wt % GO, respectively. However, insignificant changes in both mechanical strength and modulus were observed by adding GO. The results from thermal analysis indicated that the GO acts as new secondary soft segments in the polyurethane which lead to a considerable decrease in the glass transition temperature and crosslink density. The SEM morphology of the fracture surface after tensile testing showed a considerable aggregation of graphene oxide at concentrations above 0.4 wt %. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 41751. |
| |
| Keywords: | biopolymers & renewable polymers composites graphene and fullerenes mechanical properties nanotubes thermal properties |
|
|
