Mechanical and rheological properties of polypropylene/bentonite composites with stearic acid as an interface modifier |
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Authors: | Cesar Del Angel Ana B. Morales Fabiola Navarro‐Pardo Tomas Lozano Pierre G Lafleur Saul Sanchez‐Valdes Guillermo Martinez‐Colunga Eduardo Ramirez‐Vargas Sergio Alonso Roberto Zitzumbo |
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Affiliation: | 1. Instituto Tecnológico de Cd. Madero, División de Estudios de Posgrado e Investigación, Juventino Rosas y Jesús Urueta, Cd. Madero, Tamaulipas, México;2. école Polytechnique de Montréal, Chemical Engineering Department, Montreal, Quebec, Canada;3. Centro de Investigación en Química Aplicada Boulevard, Saltillo, Coahuila, México;4. Centro de Investigacion Aplicada en Tecnologias Competitivas (CIATEC), Investigación en Materiales, Guanajuato, México |
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Abstract: | In this study, we present a study of polypropylene/bentonite composites where stearic acid was used as both a surface and interface modifier during the compounding of composites. The concentration of bentonite was 1.5, 2.5, 5.0, and 10 parts per hundred. The composites were characterized by impact resistance and tensile tests, rheological analysis, the dispersion state of the filler observed by optical microscopy, and interaction between bentonite and stearic acid, as analyzed by Fourier transform infrared spectroscopy. No chemical interaction was found between bentonite and stearic acid. Composites with modified bentonite and stearic acid used as interface modifiers increased the elongation at break; these samples also showed better dispersion of the filler in comparison with the other compounds. In addition, stearic acid acted as a lubricant, favoring the interaction of the polymer with the filler and decreasing the viscosity of the compounds. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42264. |
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Keywords: | composites mechanical properties surfaces and interfaces |
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