Tarnish and corrosion behaviour of palladium-silver alloys |
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Authors: | Lynn A. O'Brien R. M. German |
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Affiliation: | (1) Materials Engineering Department, Rensselaer Polytechnic Institute, 12180-3590 Troy, New York, USA;(2) Present address: Knolls Atomic Power Laboratory, General Electric Co., P.O. Box 1072, 12301 Schenectady, New York, USA |
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Abstract: | Binary and commercial palladium-silver dental alloys show a greatest resistance to both tarnish and corrosion at compositions of between 50 and 75% Ag, most probably due to saturation of the d-electron shell in this composition range. The commercial Pd-Ag alloys have more corrosion resistance, but a lower tarnish resistance than the binary Pd-Ag alloys, due in part to the minor alloying with indium or zinc. The addition of copper increases the segregtion of silver, which adversely affects both tarnish and corrosion resistance. A solutionization heat treatment degrades tarnish resistance, but does not affect corrosion resistance. |
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