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单组分聚醋酸乙烯酯乳液的改性研究
引用本文:何瑞红,胡孝勇,陈耀.单组分聚醋酸乙烯酯乳液的改性研究[J].中国胶粘剂,2012(12):11-14.
作者姓名:何瑞红  胡孝勇  陈耀
作者单位:广西科技大学生物与化学工程学院
摘    要:以AA-PVA(乙酰乙酰化聚乙烯醇)为保护胶体、丙烯酸丁酯(BA)和叔碳酸乙烯酯(VeoVa10)为聚醋酸乙烯酯(PVAc)乳液的共聚改性单体,制得改性PVAc乳液胶粘剂。研究结果表明:当聚合温度为75℃、AA-PVA浓度为5%、w(BA)=7%和w(VeoVa10)=16%(均相对于PVAc乳液质量而言)时,相应改性PVAc乳液的剪切强度和耐水性俱佳。

关 键 词:聚醋酸乙烯酯  乙酰乙酰化聚乙烯醇  叔碳酸乙烯酯  丙烯酸丁酯

Study on modification of single component polyvinyl acetate emulsion
He Ruihong,Hu Xiaoyong,Chen Yao.Study on modification of single component polyvinyl acetate emulsion[J].China Adhesives,2012(12):11-14.
Authors:He Ruihong  Hu Xiaoyong  Chen Yao
Affiliation:(Department of Biological and Chemical Engineering,Guangxi University of Technology,Liuzhou 545006,China)
Abstract:With AA-PVA(acetoacetyl polyvinyl alcohol) as protective colloid,butyl acrylate(BA) and vinyl versatate(VeoVa10) as modified comonomers of polyvinyl acetate(PVAc) emulsion,a modified PVAc emulsion adhesive was prepared.The research results showed that the corresponding modified PVAc emulsion had both good shear strength and good water resistance when the polymerization temperature was 75 ℃,concentration of AA-PVA was 5%,mass fractions of BA and VeoVa10 were 7% and 16% in PVAc emulsion respectively.
Keywords:polyvinyl acetate(PVAc)  acetoacetyl polyvinyl alcohol(AA-PVA)  vinyl versatate(VeoVa10)  butyl acrylate(BA)
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