Synthesis, characterization and crystal structure of cis,mer-[ReH(CO)2{PPh(OMe)2}3] |
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| Authors: | Sandra Bola o, Jorge Bravo, Jesú s Castro, Marí a del Carmen Marí n,Soledad Garcí a-Font n |
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| Affiliation: | aDepartamento de Química Inorgánica, Facultade de Química, Universidade de Vigo, E-36310 Vigo, Spain |
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| Abstract: | The dicarbonylhydride complex cis,mer-[ReH(CO)2{PPh(OMe)2}3] (1) was serendipitously obtained when, in an attempt to replace a CO ligand by the phosphonite ligand PPh(OMe)2 in [ReH(CO)3(L)] (L = PPh2OCH2CH2OPPh2), this complex was treated with PPh(OMe)2 under UV irradiation. The complex 1 was characterized by IR, 1H and 31P{1H} NMR spectroscopy and by crystal structure determination. The spectroscopic features are consequent with the cis,mer configuration showed by the X-ray crystallographic analysis of the complex. The environment of the metal centre is a distorted octahedron. |
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| Keywords: | Rhenium(I) Hydride complexes Carbonyl complexes Phosphonite ligands |
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