Near-Critical-Point Thermodynamics from Shock Experiments with Porous Ni Samples

Results of experiments on the expansion of shock-compressed nickel samples into helium are presented. An isentrope with an initial pressure of 170 GPa was studied. The radiance temperature of the nickel sample and the velocity of the shock wave, generated in helium, were measured by a fast multichannel optical pyrometer; other parameters, such as the particle velocity, the pressure on the He-Ni interface, and the temperature of He were calculated using He Hugoniot (chemical plasma model). To increase the shock entropy up to a near-critical value and to intensify the process of heat-mass transfer, porous samples were used. Final states with pressures below 1.5 GPa, determined by the initial He pressure, were generated. The isobaric overheat of nickel by hot shocked helium provided an information about the nickel liquid spinodal. The change in slope of an isentrope in the pressure-particle velocity plane allowed an estimate of the point of its entrance in the two-phase region. Estimates of the critical temperature and pressure were made from peculiarities of P-T path, using various models of the nickel liquid spinodal to represent experimental data.