Temperature Coefficient of Microwave Resonance Frequency of a Low-Temperature Cofired Ceramic (LTCC) System

A family of low-temperature cofired ceramics (LTCC) based on mixtures of a commercial dielectric, MgTiO₃–CaTiO₃(designated MMT-20) and ZnO, SiO₂, and B₂O₃, has been investigated for microwave applications. The main objective was to optimize the three key properties—relative permittivity (?_r), dissipation factor (DF), and the temperature dependence of the microwave resonance frequency (τ_f)—through adjustment of the composition. A further objective was to estimate the limits on compositional variability while maintaining acceptable properties. The developed microstructures, after firing at 900°C, were studied using X-ray diffractometry and scanning electron microscopy/energy dispersive spectrometry techniques and compared with the dielectric parameters. The optimum composition (wt%) was found to lie in the ranges 45.8–44.9, ZnO; 17.25–17.55, B₂O₃; 6.95–7.05, SiO₂; and 30–30.5, MMT-20, yielding values of ?_r= 8.5–9.5, DF < 0.93 × 10^?3 ppm/K, and τ_f< ±10 ppm/K.