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Photoconductivity of organic polymer films doped with porous silicon nanoparticles and ionic polymethine dyes
Authors:N. A. Davidenko  V. A. Skrichevsky  A. A. Ishchenko  A. Yu. Karlash  E. V. Mokrinskaya
Affiliation:(1) Kiev National Taras Shevchenko University, Volodymyrs’ka ul. 64, Kiev, 01033, Ukraine;(2) Institute of Organic Chemistry, National Academy of Sciences of Ukraine, ul. Murmanska 5, Kiev, 02094, Ukraine
Abstract:Features of electrical conductivity and photoconductivity of polyvinylbutyral films containing porous silicon nanoparticles and similar films doped with cationic and anionic polymethine dyes are studied. Sensitization of the photoelectric effect by dyes with different ionicities in films is explained by the possible photogeneration of holes and electrons from dye molecules and the intrinsic bipolar conductivity of porous silicon nanoparticles. It is assumed that the electronic conductivity in porous silicon nanoparticles is higher in comparison with p-type conductivity.
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