| 新型疏水缔合水溶性聚合物的合成及溶液性能研究 |
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| 引用本文： | 王斌.新型疏水缔合水溶性聚合物的合成及溶液性能研究[J].应用化工,2011,40(4):667-669. |
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| 作者姓名： | 王斌 |
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| 作者单位： | 化学合成与污染控制四川省重点实验室西华师范大学,化学化工学院,四川,南充,637009 |
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| 摘 要： | 以四甲基乙二胺分别与溴代正十四烷/溴代正十六烷反应得到单季铵盐,再与溴丙烯反应即得到2种新型疏水单体十四烷基烯丙基二溴化四甲基乙二铵(C14PDBTMN)和十六烷基烯丙基二溴化四甲基乙二铵(C16PDBTMN)。用1HNMR和IR对单体结构进行表征,结果表明为目标化合物。以C16PDBTMN为功能性单体,和丙烯酰胺进行共聚得到新型疏水缔合物P(C16PDBTMN/AM),研究表明,新型疏水缔合物具有其独特的抗盐、抗剪切性能。
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| 关 键 词： | 双子表面活性剂 疏水缔合聚合物 不对称 |
Study on synthesis of new type of hydrophobically associating water-soluble polymer and property of the solution |
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| WANG Bin.Study on synthesis of new type of hydrophobically associating water-soluble polymer and property of the solution[J].Applied chemical industry,2011,40(4):667-669. |
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| Authors: | WANG Bin |
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| Affiliation: | WANG Bin(Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province,Department of Chemistry and Chemical Engineering,China West Normal University,Nanchong 637009,China) |
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| Abstract: | Two types of asymmetric Gemini surfactant had been synthesized by using tetramethyl ethylenediamine with n-bromotetradecane or n-bromohexadecane,then respectively reacted with 3-bromopropene again,and two types of asymmetric Gemini surfactant were gotten finally.The structures of the Gemini surfactants were identified by 1H NMR and IR spectrum.A new type of hydrophobically associating water-soluble polymer was synthesized by using the Gemini surfactants and acrylamide.This polymers has special structures an... |
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| Keywords: | Gemini surfactant hydrophobically associating water-soluble polymer asymmetric |
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