Synthesis of Nb2O5 and Ta2O5 nanopowders by means of an endo-templating method |
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| Affiliation: | 1. Faculty of Science, Department of Chemistry, University of Paderborn, Warburger Str. 100, 33098 Paderborn, Germany;2. Faculty of Science, Department of Physics, University of Paderborn, Warburger Str. 100, 33098 Paderborn, Germany;1. School of Materials Science and Engineering, Tianjin University, Tianjin 300072, China;2. School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore;3. Carle (Shanghai) Management Co., Ltd., Beijing Demonstration Center, China |
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| Abstract: | Finding efficient templates for the nanostructuring of materials is a key point. Here, the niobium (V) - and tantalum (V) oxide ceramics nanopowders have been synthesized by a hard-templating approach by using the tricalcium phosphate biomaterial (Ca3(PO4)2.xH2O) as template agent. The oxide ceramics were investigated by X-ray Diffraction (XRD), Fourier Transform Infrared (FTIR) spectroscopy, nitrogen physisorption and Scanning Electron Microscopy (SEM). It was observed that the surface properties (specific surface areas, pore volumes) of the Nb2O5 and Ta2O5 powders were strongly dependent of the amount of the Ca3(PO4)2.xH2O template previously used in the preparation of the [oxide ceramics/template] composites. For instance, with a Ca3(PO4)2.xH2O/ceramic salt weight ratio ranging from 0 to 1, the specific surface areas of Nb2O5 and Ta2O5 were gradually enhanced of 48–166 m2/g and 5–84 m2/g, respectively. The pore volumes were increased as well. The use of the eco-friendly tricalcium phosphate material (Ca3(PO4)2.xH2O) as template in the hard-templating approach may be suitable and efficient in the aim of synthesizing materials with enhanced surface properties. |
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| Keywords: | Hard-templating approach Template Niobium (V) oxide Tantalum (V) oxide Tricalcium phosphate |
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