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Fabrication of Y and Fe co-doped BaZr0.13Ti1.46O3 fine-grained ceramics for temperature-stable multilayer ceramic capacitors
Affiliation:1. Engineering Research Center of Advanced Ferroelectric Functional Materials, College of Chemistry and Chemical Engineering, Baoji University of Arts and Sciences, Key Laboratory of Phytochemistry of Shaanxi Province, Baoji 721013, PR China;2. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of Ministry of Education, Shanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xian, Shaanxi 710069, PR China;1. Laboratory of Condensed Matter and Nanostructures, Cadi Ayyad University, Marrakesh 40000, Morocco;2. Institut de Chimie de la Matière Condensée de Bordeaux, University of Bordeaux, Pessac 33600, France;3. Laboratory of Bioorganic and Macromolecular Chemistry, Cadi Ayyad University, Marrakesh 40000, Morocco;1. Department of Physics, National Institute of Technology, Rourkela 769008, India;2. Department of Physics, SVS College of Engineering, Coimbatore 642109, India;3. Department of Physics, C. V. Raman College of Engineering, Bhubaneswar 752054, India;4. Department of Physics, National Institute of Technology, Tiruchirapalli 620015, India
Abstract:Y3+ and Fe3+ co-doped BaZr0.13Ti1.46O3 powders were synthesized by wet chemical method through a precipitation process, able to control uniformity and particle size of the BaZr0.13Ti1.46O3-based particles. Fine-grained BaZr0.13Ti1.46O3 ceramics co-doped with various amounts of Y3+ and Fe3+ were prepared at low sintering temperature to yield good dielectric properties and gentle temperature stability. The co-doping effect on the microstructure and dielectric properties of BaZr0.13Ti1.46O3 ceramics were studied. Results showed the dielectric constants firstly to increase monotonically then decrease with the increase of Y3+ and Fe3+concentration. Overall, the resulting ceramics met the X8R specification when Y3+ and Fe3+ contents were 2 or 4 mol%. Moreover, the increase in Y3+ and Fe3+ doping concentration from 6 to 8 mol% satisfied the X7R specification.
Keywords:Precipitation method  Fine-grained ceramics  Dielectric properties
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