| 双环戊二烯在水溶性铑膦络合催化体系中的氢甲酰化反应 |
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| 引用本文： | 赵明,袁刚.双环戊二烯在水溶性铑膦络合催化体系中的氢甲酰化反应[J].精细化工,1996,13(4):32-34. |
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| 作者姓名： | 赵明 袁刚 |
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| 作者单位： | 化工部北京化工研究院精细化工部 |
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| 摘 要： | 研究了采用水溶性铑膦络合催化体系对双环戊二烯的氢甲酰化反应，考查了反应温度、相转移剂ＣＴＡＢ、铑催化剂浓度等对反应的影响。氢甲酰化反应的产物经ＧＣ／ＭＳ鉴定是不饱和的三环癸单醛
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| 关 键 词： | 铑膦络合物，双环戊二烯，氢甲酰化 |
WATER SOLUBLE RHODIUM PHOSPHINE COMPLEX USED IN CATALYTICHYDROFORMYLATION OFDICYCLOPENTADIENE |
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| Zhao Ming,Yuan Gang.WATER SOLUBLE RHODIUM PHOSPHINE COMPLEX USED IN CATALYTICHYDROFORMYLATION OFDICYCLOPENTADIENE[J].Fine Chemicals,1996,13(4):32-34. |
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| Authors: | Zhao Ming Yuan Gang |
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| Abstract: | The use of the water soluble rhodium phosphine complex for catalytic hydroformylation of dicyclopentadiene(DCPD) in two phase system was studied. The effects of reaction temperature, phase transfer agent (CTAB) and the concentration of rhodium catalyst were examined. The hydroformylation products, identified by GC/MS, are mainly tricyclodecenal. \ \ |
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| Keywords: | Rhodium phosphine complex Dicyclopentadiene(DCPD) Hydroformylation |
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