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Subtractive methods to form pyrite and sulfide nanostructures of Fe,Co, Ni,Cu and Zn
Affiliation:1. State Key Laboratory of Silicon Materials, Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, and School of Materials Science& Engineering, Zhejiang University, Hangzhou 310027, Zhejiang, China;2. Guangdong Engineering and Technology Research Center for Advanced Nanomaterials, School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, Guangdong, China;3. State Key Laboratory of Marine Resource Utilization in South China Sea, Hainan University, Haikou 570228, Hainan, China
Abstract:The low Z metals Fe, Co, Ni, Cu and Zn are Earth abundant, i.e. inexpensive, and their sulfides are of low toxicity. This makes them appealing candidates for materials applications requiring semiconductors or, in the case of CoS2, a metal since they can potentially be produced in large quantities and low cost. Though of great potential little work has explored how subtractive methods can be used to form nanostructured and/or porous structures in, e.g. FeS2, CoS2, NiS, Cu2S and ZnS.
Keywords:Pyrite  Sulfide  Nanostructure  Nanotube  Porous solid  Etching  Laser ablation  Anodization
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