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中孔炭材料的制备及吸附性能的研究
引用本文:栾广贵,刘振辉,荣海琴,潘鼎.中孔炭材料的制备及吸附性能的研究[J].炭素,2005(4):15-20.
作者姓名:栾广贵  刘振辉  荣海琴  潘鼎
作者单位:1. 东华大学纤维材料改性国家重点实验室,上海,200051
2. 中国石油辽阳石化分公司炼油厂,辽阳,111003
摘    要:以正硅酸乙酯为模板硅源,酚醛树脂为炭前驱体,运用模板法制备了中孔炭材料。并用红外光谱(FT—IR)、扫描电镜(SEM)、低温N2自动吸附、甲醛和VB12饱和吸附等对样品形貌、孔结构和吸附性能进行了研究。结果表明:制备的炭材料孔径集中分布在2-7nm左右,且中孔孔隙率达到74.6%,比表面积达到1012m^2/g;材料对VB12大分子有较好的吸附性能。表明通过控制正硅酸乙酯的水解条件能制备孔径集中的中孔炭材料。

关 键 词:正硅酸乙酯  酚醛树脂  凝胶  模板法  中孔炭
文章编号:1001-8948(2005)04-0015-06
收稿时间:2005-07-25
修稿时间:2005年7月25日

STUDY ON PREPARATION AND ADSORPTION PROPERTIES OF MESOPOROUS CARBONS
LUAN Guang-gui,LIU Zhen-hui,RONG Hai-qing,PAN Ding.STUDY ON PREPARATION AND ADSORPTION PROPERTIES OF MESOPOROUS CARBONS[J].Carbon,2005(4):15-20.
Authors:LUAN Guang-gui  LIU Zhen-hui  RONG Hai-qing  PAN Ding
Affiliation:1 State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,Donghua University,Shanghai, 200051,China ; 2 Liaoyang Petrochemical Corporation Refinery, Petro China, Liaoyang 111003, China
Abstract:The mesoporous carbons via the template method,tetraethoxy silane(TEOS)acted as the source of the template silica and phenol - formaldehyde resins as the carbon precursor,was prepared. FT - IR, SEM, N2 adsorption isotherms phenol formaldehyde and VB12 saturable adsorption were used to study on the pore structure and adsorption capacity of the prepared DKT carbon. The results showed that the pore diameter of porous carbon obtained by the template method was distributed in the range of 2nm~7nm,the mesoporous percent reached at 74. 6% ,with a high BET surface areas(SBET),1 012 m2/g. formaldehyde and VB12 saturation adsorption results indicated the mesoporous carbon had a better adsorption ability,especially for macromolecule. It explained that the template method could remarkably control the size of por ous carbon's diameter by controlling the hydrolysis of TEOS.
Keywords:tetraethoxy silane(TEOS)  phenol formaldehyde resin  gel  template method  mesoporous carbon
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