Quasi phase transition model of shear bands in metallic glasses |
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Authors: | Zengqian Liu Ran Li Gang Wang Sujun Wu Xuyang Lu Tao Zhang |
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Affiliation: | aKey Laboratory of Aerospace Materials and Performance, School of Materials Science and Engineering, Beihang University, Beijing 100191, People’s Republic of China;bDepartment of Materials Science and Engineering, Shanghai University, Shanghai, People’s Republic of China |
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Abstract: | A quasi phase transition model of shear bands in metallic glasses (MGs) is presented from the thermodynamic viewpoint. Energy changes during shear banding in a sample–machine system are analyzed following fundamental energy theorems. Three characteristic parameters, i.e. the critical initiation energy ΔGc, the shear band stability index k0, and the critical shear band length lc, are derived to elucidate the initiation and propagation of shear bands. The criteria for good plasticity in MGs with predominant thermodynamic arrest of shear bands are proposed as low ΔGc, large k0, and small lc. The model, combined with experimental results, is used to analyze some controversial phenomena of deformation behavior in MGs, such as the size effect, the effect of testing machine stiffness and the relationship between elastic modulus and plasticity. This study has important implications for a fundamental understanding of shear banding as well as deformation mechanisms in MGs and provides a theoretical basis for improving the ductility of MGs. |
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Keywords: | Shear bands Metallic glasses Thermodynamics Phase transformations Plastic deformation |
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